Product ID:SQUIBS S PRODUCTS, M-1
MSDS Date:11/03/1985
FSC:1375
NIIN:00N034487
MSDS Number: BQBRG

E I DU PONT DE NEMOURS & CO INC

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515;302-774-3120

Preparer: PRODUCT MGR, EP, F & FP

Cage: B0589

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

HE SHOULD CONSULT THE MANUFACTURER BEFORE USE.

RTECS: 9999999ZZ

LEAD DINITROORTHOCRESYLATE

CAS: 79357-62-3

OSHA PEL 0.15 MG/M3 AS LEAD

ACGIH TLV: 0.15 MG/M3 AS LEAD

POTASSIUM PERCHLORATE

CAS: 7778-74-7

RTECS: SC9700000

BARIUM PEROXIDE

CAS: 1304-29-6

RTECS: CR0175000

SMOKELESS POWDER

BLACK GUN POWDER

BASIC LEAD PHOSPHITE

CAS: 12141-20-7

OSHA PEL 0.15 MG/M3 AS LEAD

ACGIH TLV: 0.15 MG/M3 AS LEAD

BORON

CAS: 7440-42-8

RTECS: ED7350000

OSHA PEL 15 MG/M3 (AS OXIDE)

ACGIH TLV: 10 MG/M3 (AS OXIDE)

MAGNESIUM

CAS: 7439-95-4

RTECS: OM2100000

SELENIUM (SARA III)

CAS: 7782-49-2

RTECS: VS7700000

OSHA PEL 0.2 MG/M3

ACGIH TLV: 0.2 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ALUMINUM (SARA III)

CAS: 7429-90-5

RTECS: BD0330000

OSHA PEL 15MG/M3 DUST;5 FUME

ACGIH TLV: 10MG/M3 DUST;5 FUME

COMMERCIAL BRONZE

ENTIRE LEAFLETS(S) "DO'S & DON'TS" INSTRUCTIONS

RTECS: 9999999ZZ

HAVE ANY QUESTIONS OR DOUBTS AS TO HOW TO USE ANY

RTECS: 9999999ZZ

SUPERVISOR, OR THE MFR IF YOU DO NOT HAVE A

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:DU PONT SPECIALTY ELECTRIC DETONATORS
"S" PRODUCTS & THEIR COMPONENTS DO NOT PRESENT HLTH HAZS IN NORM
HNDLNG & USE. HOWEVER, THE PRODS ARE SQUIBS & DECOMP MAY CAUSE SEV
INJURY, INCL DEATH. OVEREXPOS TO LEAD MAY CAUSE ADVERSE EFTS TO
BLOODFORMING, NERV, URINARY, REPROD SYS, INCL EMBRYOTOXIC EFTS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SYMPS MAY INCL LOSS OF APPETITIE,
ANEMIA, DISTURB OF SLEEP & FATIGUE. FOR ADDNL INFO SEE THE OSHA
LEAD STANDARD 29CFR1910.1025. NITROGEN OXIDES GENERATED DURING USE
ARE SKIN, EYE & RESP SYS I RRITANTS. SYSTEMIC TOX RSLTG FROM
OXIDATION OF LUNG TISS INCL EMPHYSEMA, BRONCH & BRONCHOPNEUMONIA.
ACUTE (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:IF FUMES ARE INHALED, REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTF RESP, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING
IS DIFFICULT, GIVE O*2. CALL MD. INGEST:CALL MD IMMEDIATELY .
SKIN:FLUS H W/COPIOUS AMOUNTS OF WATER. CALL MD . EYE:IMMEDIATELY
FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINS. SEEK ASSISTANCE
FROM MD .

Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. DO NOT FIGHT FIRE. ISOLATE AREA. EVACUATE PERS TO A SAFE AREA.
GUARD AGAINST INTRUDERS. PRDCES SHRAPNEL.
Unusual Fire/Explosion Hazard:WILL DETONATE WHEN EXPOSED TO HEAT/FLAME.
PRODUCE SHRAPNEL. HAZARDOUS GASES PRODUCED IN FIRE MAY INCLUDE LEAD
FUMES, NITROGEN OXIDES & COMPOUNDS OF B & SE.

Spill Release Procedures:REVIEW FIRE/EXPLOS HAZ & SFTY PRECS. USE
APPROP PERSONAL PROT EQUIP. CONTROL ACCESS TO AREA & REMOVE SOURCES
OF FRICTION, IMPACT, HEAT, LOW LEVEL ELEC CURRENT, ELECTROSTATIC OR
RF ENERGY. REFER TO MFR S "DO'S & DON'TS" INSTRUCTIONS & (SUPP
DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFER TO MANUFACTURER'S "DO'S &
DON'TS" INSTRUCTIONS & WARNINGS SUPPLIED W/EACH PRODUCT SHIPMENT.
Other Precautions:ALL EXPLOSIVES ARE DANGEROUS & MUST BE CAREFULLY
HNDLD & USED FOLLOWING APPRVD SFTY PROCS EITHER BY OR UNDER
DIRECTION OF COMPETENT, EXPER PERS I/A/W ALL APPLIC FED, STATE &
LOC LAWS, REGS & ORDINANCE S. IF, AFTER CAREFULLY READING (SUP DAT)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:COTTON SOCKS & CONDUCTIVE SOLED SHOES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:EXPOSURE CAN LEAD TO DEATH FROM ASPHYXIA OR PULMONARY
EDEMA. IN ANIMALS, NITROGEN OXIDE CAUSED METHEMOGLOBINEMIA, WAS NOT
CARCINOGENIC, BUT SHOWED EMBRYOTOXIC ACTIVITY & REPRODUCTIVE E
FFECTS. SPILL PROC:WARNING SUPPLIED W/EACH PRODUCT SHIPMENT.

HCC:E2
Appearance and Odor:ALUMINUM OR COMMERCIAL BRONZE SHELLS W/ATTACHED
INSULATED COPPER LEG WIRES.

Stability Indicator/Materials to Avoid:NO
IMCOMPATIBLE W/ACIDS & ALKALIES.
Stability Condition to Avoid:DETONATES W/FRICTION, IMPACT, HEAT, LOW
LEVEL ELECTRICAL CURRENT, ELECTROSTATIC OR RF ENERGY.
Hazardous Decomposition Products:DETONATION PRDCES SHRAPNEL. HAZ GASES
PRDCED MAY CONTAIN LEAD FUMES, CARBON MONOXIDE, NITROGEN OXIDES &
CMPDS OF B & SE.

Waste Disposal Methods:CONSULT AN EXPLOSIVE MFR FOR RECOMMENDED METHODS
OF DESTROYING EXPLOSIVE MATERIAL. COMPLY W/APPLICABLE FEDERAL
REGULATIONS UNDER THE AUTHORITY OF THE RCRA (40CFR PARTS 260-271).
DISPOSAL MUST BE IN AC CORDANCE W/FEDERAL, STATE & LOCAL REGS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.